Elucidation of the role of metal-to-ring charge-transfer excited states in the deactivation of photoexcited ruthenium porphyrin carbonyl complexes
Document Type
Article
Publication Title
Chemical Physics Letters
Abstract
Deactivation of the lowest excited triplet state, 3(π, π*), of the Ru(II) porphyrins RuP(CO)(L) is more strongly dependent on temperature than decay of 3(π, π*) in Pt(II)P and H2P (metal-free) complexes containing the same macrocycle P. This and other observations support the proposal that 3(π, π*) in the RuP(CO)(L) complexes decays in part via a metal-to-ring (d, π*) charge-transfer excited state at higher energy. © 1988.
First Page
235
Last Page
240
DOI
10.1016/0009-2614(88)85091-7
Publication Date
6-3-1988
Recommended Citation
Rodriguez, Juan; McDowell, Lynda; and Holten, Dewey, "Elucidation of the role of metal-to-ring charge-transfer excited states in the deactivation of photoexcited ruthenium porphyrin carbonyl complexes" (1988). Basic Sciences Faculty Publications. 215.
https://doi.org/10.1016/0009-2614(88)85091-7
https://collections.uhsp.edu/basic-sciences_pubs/215